Could easy be. When calibrating the accuvolume, definitely do it with the Aim command pro off (just power off the monitor, leave the console switch in auto). When AC Pro is off, it should pass through all the sensors (flow, pressure) to the Raven rate controller. If you look under the sprayer near your solution pump you should see the rate controller mounted to a bracket. You'll see a mess of cables. Basically the sprayers harness normally connects directly to the Raven controller, but with Aim Command Pro, a harness coming from the back of the sprayer will plug in between the sprayer harness and the Raven controller. You could try unplugging this Aim Command Pro intercept plugs and plug the sprayer harness directly into the Raven Rate controller. This will remove Aim Command Pro from the equation, at least for testing. In this configuration I'm not sure if the poppets will open when you turn on the booms, but certainly the pump should go.
Definitely sounds like it could be an Aim Command Pro wiring problem. when I was fighting this issue, it would shut the pump off even if the Aim Command Pro monitor was off because the various sensor signals that were supposed to be passed through were glitching. My harness had damage right at the front of the bottom left arm that lifts the rack. The cable had pulled underneath the arm and as the rack lifted up it would stretch the harness, if that makes sense.
A new Aim Command Pro harness was $1600, which is a lot of money but if you're not wanting to make your own harness like I did, it's probably easiest to just pay for it. I'd have to spend some time documenting the harness again for you if you want to run your own wires (and if you have some DT and DTM Deutsch pins available).